Synthesis and characterization of hexa-coordinated Sn(IV) complexes of meso-aryl dipyrrins
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
Synthesis and characterization of hexa-coordinated Sn(IV) complexes of meso-aryl dipyrrins
|
|
Creator |
SHARMA, R
GHOSH, A WOLFRAM, B BRORING, M RAVIKANTH, M |
|
Subject |
METAL-ORGANIC FRAMEWORKS
STRUCTURAL-CHARACTERIZATION HETEROLEPTIC COPPER DIPYRROMETHENE COMPLEXES COBALT COMPLEXES SILVER SALTS BODIPY DYES CHEMISTRY PORPHYRINS POLYMERS |
|
Description |
Our successful synthesis of the first examples of Sn(IV) complexes of meso-aryl dipyrrins is reported. Sn(IV) dipyrrins are synthesized by treating meso-aryl dipyrrins with readily available SnCl2 center dot 2H(2)O in pyridine at reflux temperature and isolated as pure complexes by recrystallization. The X-ray structure revealed that the complex is hexa-coordinated and the Sn(IV) ion is coordinated to two dipyrrin units and two chlorides with overall appearance of a butterfly like structure. The complexes are stable in solution and characterized by spectral and electrochemical techniques.
|
|
Publisher |
ROYAL SOC CHEMISTRY
|
|
Date |
2014-10-15T08:29:18Z
2014-10-15T08:29:18Z 2013 |
|
Type |
Article
|
|
Identifier |
DALTON TRANSACTIONS, 42(16)5627-5630
http://dx.doi.org/10.1039/c3dt00031a http://dspace.library.iitb.ac.in/jspui/handle/100/14685 |
|
Language |
en
|
|