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Charged, but Found "Not Guilty": Innocence of the Suspect Bridging Ligands [RO(O)CNNC(O)OR](2-) = L2- in [(acac)(2)Ru(mu-L)Ru(acac)(2)](n), n = +,0,-,2-

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Title Charged, but Found "Not Guilty": Innocence of the Suspect Bridging Ligands [RO(O)CNNC(O)OR](2-) = L2- in [(acac)(2)Ru(mu-L)Ru(acac)(2)](n), n = +,0,-,2-
 
Creator ROY, S
SARKAR, B
IMRICH, HG
FIEDLER, J
ZALIS, S
JIMENEZ-APARICIO, R
URBANOS, FA
MOBIN, SM
LAHIRI, GK
KAIM, W
 
Subject DINUCLEAR RUTHENIUM COMPLEXES
MOLECULAR-ORBITAL METHODS
ANION-RADICAL COMPLEXES
MIXED-VALENT COMPLEXES
OPTICAL ATTENUATION
BASIS-SETS
BEHAVIOR
DIMERS
ENERGY
REDOX
 
Description Neutral diastereoisomeric diruthenium(III) complexes, meso- and rae-[(acac)(2)Ru(mu-adc-OR)Ru(acac)(2)) (acac(-) = 2,4-pentanedionato and adc-OR2- = dialkylazodicarboxylato = [RO(O)CNNC(O)OR](2-), R = tert-butyl or isopropyl), were obtained from electron transfer reactions between Ru(acac)(2)(CH3CN)(2) and azodicarboxylic acid diallcyl esters (adc-OR). The mew,P isomer 3 with R = isopropyl was structurally characterized, revealing two deprotonated and N-N coupled carbamate functions in a reduced dianionic bridge with d(N-N) = 1.440(5) angstrom. A rather short distance of 4.764 angstrom has been determined between the two oxidized, antiferromagnetically coupled Ru-III centers. The rac isomer 4 with R = isopropyl exhibited stronger antiferromagnetic coupling. While the oxidation of the neutral compounds was fully reversible only for 3 and 4, two well-separated (10(8) < K-c < 10(10)) reversible one-electron reduction steps produced monoanionic intermediates 1(-)-4(-) with intense (epsilon approximate to 3000 M-1 cm(-1)), broad (Delta nu(1/2) approximate to 3000 cm(-1)) absorptions in the near-infrared (NIR) region around 2000 nm. The absence of electron paramagnetic resonance (EPR) signals even at 4 K favors the mixed-valent formulation Ru-II(adc-OR2-)Ru-III with innocently behaving bridging ligands over the radical-bridged alternative Ru-II(adc-OR center dot-)Ru-II, a view which is supported by the metal-centered spin as calculated by density functional theory (DFT) for the methyl ester model system. The second reduction of the complexes causes the NIR absorption to disappear completely, the EPR silent oxidized forms 3(+) and 4(+), calculated with asymmetrical spin distribution, do not exhibit near infrared (NIR) activity. The series of azo-bridged diruthenium complex redox systems [(acac)(2)Ru(mu-adc-R)Ru(acac)(2)](n) (n = +,0,-,2-), [(bpy)(2)Ru(mu-adc-R)Ru(bpy)(2)](k) (k = 4+,3+,2+,0,2-), and [(acac)(2)Ru(mu-dihR)Ru(acac)(2)](m) (m = 2+,+,0,-,2-; dih-R2- = 1,2-diiminoacylhydrazido(2-)) is being compared in terms of electronic structure and identity of the odd-electron intermediates, revealing the dichotomy of innocent vs noninnocent behavior.
 
Publisher AMER CHEMICAL SOC
 
Date 2014-10-15T10:52:02Z
2014-10-15T10:52:02Z
2012
 
Type Article
 
Identifier INORGANIC CHEMISTRY, 51(17)9273-9281
http://dx.doi.org/10.1021/ic300809w
http://dspace.library.iitb.ac.in/jspui/handle/100/14792
 
Language en