Decarbonylative Halogenation by a Vanadium Complex
DSpace at IIT Bombay
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Title |
Decarbonylative Halogenation by a Vanadium Complex
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Creator |
RANA, S
HAQUE, R SANTOSH, G MAITI, D |
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Subject |
ACTIVE DNA DEMETHYLATION
MECHANISTIC CONSIDERATIONS DEPENDENT HALOPEROXIDASES MEDIATED DEFORMYLATION OXIDATIVE HALOGENATION FUNCTIONAL MODELS HYDROGEN-PEROXIDE ACID BIOSYNTHESIS CHLORINATION |
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Description |
Metal-catalyzed halogenation of the C-H bond and decarbonylation of aldehyde are conventionally done in nature. However, metal-mediated decarbonylative halogenation is unknown. We have developed the first metal-mediated decarbonylative halogenation reaction starting from the divanadium oxoperoxo complex K3V25+(O-2(2-))(4)(O2-)(2)(mu-OH) (1). A concerted decarbonylative halogenation reaction was proposed based on experimental observations.
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Publisher |
AMER CHEMICAL SOC
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Date |
2014-10-15T12:08:00Z
2014-10-15T12:08:00Z 2013 |
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Type |
Article
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Identifier |
INORGANIC CHEMISTRY, 52(6)2927-2932
http://dx.doi.org/10.1021/ic302611a http://dspace.library.iitb.ac.in/jspui/handle/100/14865 |
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Language |
en
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