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Decarbonylative Halogenation by a Vanadium Complex

DSpace at IIT Bombay

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Field Value
 
Title Decarbonylative Halogenation by a Vanadium Complex
 
Creator RANA, S
HAQUE, R
SANTOSH, G
MAITI, D
 
Subject ACTIVE DNA DEMETHYLATION
MECHANISTIC CONSIDERATIONS
DEPENDENT HALOPEROXIDASES
MEDIATED DEFORMYLATION
OXIDATIVE HALOGENATION
FUNCTIONAL MODELS
HYDROGEN-PEROXIDE
ACID
BIOSYNTHESIS
CHLORINATION
 
Description Metal-catalyzed halogenation of the C-H bond and decarbonylation of aldehyde are conventionally done in nature. However, metal-mediated decarbonylative halogenation is unknown. We have developed the first metal-mediated decarbonylative halogenation reaction starting from the divanadium oxoperoxo complex K3V25+(O-2(2-))(4)(O2-)(2)(mu-OH) (1). A concerted decarbonylative halogenation reaction was proposed based on experimental observations.
 
Publisher AMER CHEMICAL SOC
 
Date 2014-10-15T12:08:00Z
2014-10-15T12:08:00Z
2013
 
Type Article
 
Identifier INORGANIC CHEMISTRY, 52(6)2927-2932
http://dx.doi.org/10.1021/ic302611a
http://dspace.library.iitb.ac.in/jspui/handle/100/14865
 
Language en