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Detecting Bifurcations in an Electrochemical Cell Employing an Assisted Reference Model Strategy

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Title Detecting Bifurcations in an Electrochemical Cell Employing an Assisted Reference Model Strategy
 
Creator RAMIREZ-ALVAREZ, E
RAMIREZ, MC
RICO-MARTINEZ, R
GONZALEZ-FIGUEREDO, C
PARMANANDA, P
 
Subject SYSTEM
INSTABILITIES
 
Description Bifurcations are detected in experiments involving the electrochemical oxidation of copper in phosphoric acid. Ideally, a bifurcation detection protocol requires a model with good qualitative and quantitative prediction capabilities that is also able to reproduce the drift inherent to the electrochemical experiment. A generic protocol for manipulation of nonlinear systems is proposed to achieve this goal. This protocol is based on a good qualitative predictor coupled to a modified Kalman filter that corrects the quantitative errors of the model point by point, adapting to the slowly varying conditions imposed by the electrochemical drift.
 
Publisher AMER CHEMICAL SOC
 
Date 2014-10-15T12:10:02Z
2014-10-15T12:10:02Z
2013
 
Type Article
 
Identifier JOURNAL OF PHYSICAL CHEMISTRY A, 117(3)535-540
http://dx.doi.org/10.1021/jp310127a
http://dspace.library.iitb.ac.in/jspui/handle/100/14869
 
Language en