Detecting Bifurcations in an Electrochemical Cell Employing an Assisted Reference Model Strategy
DSpace at IIT Bombay
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Title |
Detecting Bifurcations in an Electrochemical Cell Employing an Assisted Reference Model Strategy
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Creator |
RAMIREZ-ALVAREZ, E
RAMIREZ, MC RICO-MARTINEZ, R GONZALEZ-FIGUEREDO, C PARMANANDA, P |
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Subject |
SYSTEM
INSTABILITIES |
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Description |
Bifurcations are detected in experiments involving the electrochemical oxidation of copper in phosphoric acid. Ideally, a bifurcation detection protocol requires a model with good qualitative and quantitative prediction capabilities that is also able to reproduce the drift inherent to the electrochemical experiment. A generic protocol for manipulation of nonlinear systems is proposed to achieve this goal. This protocol is based on a good qualitative predictor coupled to a modified Kalman filter that corrects the quantitative errors of the model point by point, adapting to the slowly varying conditions imposed by the electrochemical drift.
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Publisher |
AMER CHEMICAL SOC
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Date |
2014-10-15T12:10:02Z
2014-10-15T12:10:02Z 2013 |
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Type |
Article
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Identifier |
JOURNAL OF PHYSICAL CHEMISTRY A, 117(3)535-540
http://dx.doi.org/10.1021/jp310127a http://dspace.library.iitb.ac.in/jspui/handle/100/14869 |
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Language |
en
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