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Iron-Mediated Decarboxylative Trifluoromethylation of alpha,beta-Unsaturated Carboxylic Acids with Trifluoromethanesulfinate

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Title Iron-Mediated Decarboxylative Trifluoromethylation of alpha,beta-Unsaturated Carboxylic Acids with Trifluoromethanesulfinate
 
Creator PATRA, T
DEB, A
MANNA, S
SHARMA, U
MAITI, D
 
Subject Synthetic methods
Cross-coupling
Radical reactions
Trifluoromethylation
Iron
COPPER-CATALYZED TRIFLUOROMETHYLATION
ARYL BORONIC ACIDS
MEDICINAL CHEMISTRY
BOND-FORMATION
OXIDATIVE TRIFLUOROMETHYLATION
ROOM-TEMPERATURE
SODIUM TRIFLUOROMETHANESULFINATE
ALLYLIC TRIFLUOROMETHYLATION
PHOTOREDOX CATALYSIS
ARYLBORONIC ACIDS
 
Description A sustainable FeCl3-mediated method has been developed for the decarboxylative trifluoromethylation of ,-unsaturated carboxylic acids by using NaSO2CF3 as an economic and stable CF3 source. The reaction proceeds under mild condition and tolerates various functional groups. Advantageously, this method does not require an inert atmosphere and proceeds well in air at ambient temperature.
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2014-10-15T13:08:40Z
2014-10-15T13:08:40Z
2013
 
Type Article
 
Identifier EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013(24)5247-5250
1434-193X
1099-0690
http://dx.doi.org/10.1002/ejoc.201300473
http://dspace.library.iitb.ac.in/jspui/handle/100/14966
 
Language en