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Nickel-catalyzed decyanation of inert carbon-cyano bonds

DSpace at IIT Bombay

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Field Value
 
Title Nickel-catalyzed decyanation of inert carbon-cyano bonds
 
Creator PATRA, T
AGASTI, S
AKANKSHA
MAITI, D
 
Subject TRANSITION-METAL COMPLEX
C-CN BOND
REDUCTIVE DECYANATION
IRON-COMPLEX
ARYL ETHERS
CLEAVAGE
CARBOCYANATION
ACTIVATION
ALKYNES
NI
 
Description Nickel catalyzed decyanation of aryl and aliphatic cyanides with hydrosilane as the hydride source has been developed. This method is easy to handle, scalable and can be carried out without a glove box. The method has been applied in the cyanide directed functionalization reaction and alpha-substitution of benzyl cyanide.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2014-10-15T13:09:41Z
2014-10-15T13:09:41Z
2013
 
Type Article
 
Identifier CHEMICAL COMMUNICATIONS, 49(1)69-71
http://dx.doi.org/10.1039/c2cc36883h
http://dspace.library.iitb.ac.in/jspui/handle/100/14968
 
Language en