A Predictably Selective Nitration of Olefin with Fe(NO3)(3) and TEMPO
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
A Predictably Selective Nitration of Olefin with Fe(NO3)(3) and TEMPO
|
|
Creator |
NAVEEN, T
MAITY, S SHARMA, U MAITI, D |
|
Subject |
ORGANIC-SYNTHESIS
IRON ALKENES CARBON NITROALKANES NITROOLEFINS DERIVATIVES HETEROATOM CATALYSIS STYRENES |
|
Description |
Ferric nitrate with catalytic TEMPO has been identified as a useful reagent for regio- and stereoselective nitration of a wide variety of aromatic, aliphatic, and heteroaromatic olefins. This reaction provided nitroolefins in preparatively useful yields with excellent E-selectivity. Due to its mild nature and operational simplicity, the present protocol is expected to find application in synthetic setup.
|
|
Publisher |
AMER CHEMICAL SOC
|
|
Date |
2014-10-15T14:13:29Z
2014-10-15T14:13:29Z 2013 |
|
Type |
Article
|
|
Identifier |
JOURNAL OF ORGANIC CHEMISTRY, 78(12)5949-5954
http://dx.doi.org/10.1021/jo400598p http://dspace.library.iitb.ac.in/jspui/handle/100/15074 |
|
Language |
en
|
|