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Coordination complexes based on 4-aminobenzonitrile with different dimensionalities

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Title Coordination complexes based on 4-aminobenzonitrile with different dimensionalities
 
Creator NASANI, R
SAHA, M
MOBIN, SM
KIRILLOV, AM
MUKHOPADHYAY, S
 
Subject Self-assembly
Supramolecular chemistry
Coordination polymer
4-Aminobenzonitrile
METAL-ORGANIC FRAMEWORK
MAGNETIC-PROPERTIES
CRYSTAL-STRUCTURES
MOLECULAR-STRUCTURES
BUILDING-BLOCKS
POLYMERS
LIGANDS
TRICYANOMETHANIDE
CHEMISTRY
TCNE
 
Description Reaction of 4-aminobenzonitrile with different transition metal ions in the presence of chloride provides metal complexes of different dimensionalities. Whereas platinum forms a 0-D mononuclear complex {[PtCl2(4-ABN)(2)} 1, three new coordination polymers {[Zn(4-ABN)(2)(H2O)(2)](ClO4)(2)} (n) 2, {[Cu(4-ABN)(2)(MeOH)(2)](ClO4)(2)} (n) 3, and {Cd(4-ABN)Cl-2} (n) 4 have been synthesized and characterized.Complexes 2 and 3 crystallize in 1-D polymeric chains, whereas 4 forms a 3-D coordination network, based on fused 12-membered rings of cadmium and chloride. A topological analysis of 4 reveals a uninodal five-connected network with the point (Schlafli) symbol of (4(4)x6(6)) and the nov (5/4/08) topology. All the isolated complexes were characterized by IR, elemental, and X-ray single crystal structural analyses. Complexes 1, 2, and 4 were additionally characterized by NMR spectroscopy.
 
Publisher TAYLOR & FRANCIS LTD
 
Date 2014-10-15T14:15:34Z
2014-10-15T14:15:34Z
2013
 
Type Article
 
Identifier JOURNAL OF COORDINATION CHEMISTRY, 66(9)1602-1615
http://dx.doi.org/10.1080/00958972.2013.783698
http://dspace.library.iitb.ac.in/jspui/handle/100/15078
 
Language en