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An efficient dehydroxymethylation reaction by a palladium catalyst

DSpace at IIT Bombay

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Title An efficient dehydroxymethylation reaction by a palladium catalyst
 
Creator MODAK, A
NAVEEN, T
MAITI, D
 
Subject ALCOHOL OXIDATION
AEROBIC OXIDATION
HYDROGEN-PRODUCTION
REDUCTIVE CLEAVAGE
MOLECULAR-OXYGEN
ARYL ETHERS
DECARBONYLATION
ALDEHYDES
BONDS
DNA
 
Description A general method for selective dehydroxymethylation has been discovered by using widely available Pd(OAc)(2). The present study offers a new synthetic strategy for the regioselective functionalization by employing the steric, electronic and coordinating nature of the hydroxymethyl (-CH2OH) group temporarily.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2014-10-15T15:31:56Z
2014-10-15T15:31:56Z
2013
 
Type Article
 
Identifier CHEMICAL COMMUNICATIONS, 49(3)252-254
http://dx.doi.org/10.1039/c2cc36951f
http://dspace.library.iitb.ac.in/jspui/handle/100/15160
 
Language en