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Synthesis, structure and redox property of first 1,2,3-triselenole

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Title Synthesis, structure and redox property of first 1,2,3-triselenole
 
Creator MATHUR, P
RAI, DK
TAUQEER, M
JOSHI, RK
LAHIRI, GK
MOBIN, SM
 
Subject Chalcogenole
Triselenole
Demetallation
Cyclic voltammetry
RAY CRYSTAL-STRUCTURE
RADICAL-CATION
RING-SYSTEMS
COMPLEXES
SELENIUM
DERIVATIVES
IDENTITY
LIGANDS
ATOMS
ACID
 
Description Photolysis of [Fe3Se2(CO)(9)] with 3-ferrocenylpropynal in hexane yields an adduct of [Fe2Se2(CO)(6)] and FcC(2)CHO, [(CO)(6)Fe-2{mu-SeC(Fc)]=C(CHO)Se}] (1). Subsequent reaction of 1 with [Fe2Se2(CO)(6)] in presence of excess of Me3NO center dot 2H(2)O in THF leads to formation of a novel 5-ferrocenyl-4-carbaldehyde-1,2,3-triselenole (2). Its electrochemistry has been investigated by cyclic voltammetry, which shows two successive quasi-reversible oxidations. (C) 2012 Elsevier B. V. All rights reserved.
 
Publisher ELSEVIER SCIENCE SA
 
Date 2014-10-15T15:55:28Z
2014-10-15T15:55:28Z
2012
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 721144-147
http://dx.doi.org/10.1016/j.jorganchem.2012.09.009
http://dspace.library.iitb.ac.in/jspui/handle/100/15207
 
Language en