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Reaction of ruthenium phenyl acetylide with iron-chalcogen clusters and iron pentacarbonyl

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Title Reaction of ruthenium phenyl acetylide with iron-chalcogen clusters and iron pentacarbonyl
 
Creator MATHUR, P
RAGHUVANSHI, A
JI, RS
MOBIN, SM
 
Subject Ruthenium acetylide
Photolysis
Adduct
Mixed metal cluster
MIXED-METAL CLUSTERS
STRUCTURAL-CHARACTERIZATION
SPECTROSCOPIC CHARACTERIZATION
HETEROMETALLIC CLUSTERS
FLUXIONAL BEHAVIOR
CARBONYL CLUSTER
SE
TE
MO
COMPLEXES
 
Description Photolysis of a THF solution containing ruthenium acetylide [(eta(5)-C5H5)Ru(PPh3)(2)(eta(1)-C CPh)] with [Fe-3(CO)(9)(mu(3)-Se)(2)] cluster affords an adduct [{mu-SeC(CpRu(PPh3)(CO))=C(Ph)Se)(CO)(6)Fe-2] (1), while under similar reaction condition with [Fe-3(CO)(9)(mu(3)-Te)(2)] cluster a Ru-inserted product [(eta(5)-C5H5)(PPh3)(eta(1)-C CPh)RuFe2(mu(3)-Te)(2)(CO)(6)] (2) was obtained. Under thermal condition [(eta(5)-C5H5)Ru(PPh3)(2)(eta(1)-C CPh)] react with Fe(CO)(5) to give an acetylide stabilised Fe2Ru mixed metal cluster [(eta(5)-C5H5)RuFe2(CO)(7)(eta(2):eta(2):eta(1)-C=CPh)], (3). (C) 2013 Elsevier B.V. All rights reserved.
 
Publisher ELSEVIER SCIENCE SA
 
Date 2014-10-15T15:56:28Z
2014-10-15T15:56:28Z
2013
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 73155-60
http://dx.doi.org/10.1016/j.jorganchem.2013.02.001
http://dspace.library.iitb.ac.in/jspui/handle/100/15209
 
Language en