Reaction of ruthenium phenyl acetylide with iron-chalcogen clusters and iron pentacarbonyl
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
Reaction of ruthenium phenyl acetylide with iron-chalcogen clusters and iron pentacarbonyl
|
|
Creator |
MATHUR, P
RAGHUVANSHI, A JI, RS MOBIN, SM |
|
Subject |
Ruthenium acetylide
Photolysis Adduct Mixed metal cluster MIXED-METAL CLUSTERS STRUCTURAL-CHARACTERIZATION SPECTROSCOPIC CHARACTERIZATION HETEROMETALLIC CLUSTERS FLUXIONAL BEHAVIOR CARBONYL CLUSTER SE TE MO COMPLEXES |
|
Description |
Photolysis of a THF solution containing ruthenium acetylide [(eta(5)-C5H5)Ru(PPh3)(2)(eta(1)-C CPh)] with [Fe-3(CO)(9)(mu(3)-Se)(2)] cluster affords an adduct [{mu-SeC(CpRu(PPh3)(CO))=C(Ph)Se)(CO)(6)Fe-2] (1), while under similar reaction condition with [Fe-3(CO)(9)(mu(3)-Te)(2)] cluster a Ru-inserted product [(eta(5)-C5H5)(PPh3)(eta(1)-C CPh)RuFe2(mu(3)-Te)(2)(CO)(6)] (2) was obtained. Under thermal condition [(eta(5)-C5H5)Ru(PPh3)(2)(eta(1)-C CPh)] react with Fe(CO)(5) to give an acetylide stabilised Fe2Ru mixed metal cluster [(eta(5)-C5H5)RuFe2(CO)(7)(eta(2):eta(2):eta(1)-C=CPh)], (3). (C) 2013 Elsevier B.V. All rights reserved.
|
|
Publisher |
ELSEVIER SCIENCE SA
|
|
Date |
2014-10-15T15:56:28Z
2014-10-15T15:56:28Z 2013 |
|
Type |
Article
|
|
Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 73155-60
http://dx.doi.org/10.1016/j.jorganchem.2013.02.001 http://dspace.library.iitb.ac.in/jspui/handle/100/15209 |
|
Language |
en
|
|