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Synthesis and characterization of a novel unfused 1, 4-diselenine

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Title Synthesis and characterization of a novel unfused 1, 4-diselenine
 
Creator MATHUR, P
JI, RS
TAUQEER, M
LAHIRI, GK
MOBIN, SM
 
Subject Microwave irradiation
1,4-Diselenine
Clusters
Crystal structure
PHOTOCHEMICAL-REACTIONS
DERIVATIVES
FE(CO)(5)
FERROCENYLACETYLENE
FRAGMENTATION
1,4-DITHIINS
ALKYNES
SULFUR
 
Description Microwave irradiation of toluene solution of mixed-chalcogen clusters [Fe-3(CO)(9)(mu(3)-E)(mu(3)-E')] (E, E' - S, Se or Te, and E not equal E') with ethynylferrocene and TMNO center dot 2H(2)O afforded 2,5-diferrocenyldiselenine (1), 2,5-diferrocenylselenophene (2), 2,6-diferrocenylthiine (4) and 2,5-diferrocenylthiophene (5), and the adducts Fe-2(CO)(6){(mu-E)(2)C(Fc) = CH} [E = Se(3), S(6)].1-6 have been characterized by IR, and H-1 NMR and C-13 NMR spectroscopy. Structure 1 was established by single crystal X-ray diffraction method. (C) 2012 Elsevier B.V. All rights reserved.
 
Publisher ELSEVIER SCIENCE SA
 
Date 2014-10-15T15:57:29Z
2014-10-15T15:57:29Z
2012
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 721186-189
http://dx.doi.org/10.1016/j.jorganchem.2012.09.006
http://dspace.library.iitb.ac.in/jspui/handle/100/15211
 
Language en