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Formation of (E)-[FcC(PS2(OR)(2))= CH(PS2(OR)(2))] (R = Me, Et, Pr-i) in photolytic reactions of ferrocenylacetylene and [(RO)(2)PS2H] in hexane/alcohols: Experimental and DFT study

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Title Formation of (E)-[FcC(PS2(OR)(2))= CH(PS2(OR)(2))] (R = Me, Et, Pr-i) in photolytic reactions of ferrocenylacetylene and [(RO)(2)PS2H] in hexane/alcohols: Experimental and DFT study
 
Creator MATHUR, P
JI, RS
PATHAK, B
MOBIN, SM
 
Subject Ethene
Dialkyldithiophosphate
Crystal structure
DFT
ORGANIC SULFUR COMPOUNDS
UNSATURATED-COMPOUNDS
OXIDATION REACTIONS
BIOLOGICAL-ACTIVITY
SOLID-STATE
THIOLS
DENSITY
ACID
OLIGODEOXYNUCLEOTIDES
PHOSPHORODITHIOATES
 
Description Photochemical reactions of ferrocenylacetylene with dialkyldithiophosphoric acid in hexane at low temperature led to the formation of (E)-[FcC(PS2(OR)(2))-CH(PS2(OR)(2))] (R = Me, Et, Pr-i). Formation of these compounds have been studied experimentally and computationally in different solvents. (C) 2013 Elsevier B.V. All rights reserved.
 
Publisher ELSEVIER SCIENCE SA
 
Date 2014-10-15T15:58:29Z
2014-10-15T15:58:29Z
2013
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 74846-50
0022-328X
1872-8561
http://dx.doi.org/10.1016/j.jorganchem.2013.04.021
http://dspace.library.iitb.ac.in/jspui/handle/100/15213
 
Language en