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Oxidation of Carbene-Derived Selenium Diiodide with Silver Tetrafluoroborate Isolation of Iodonium Ion Complexes with Selones

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Title Oxidation of Carbene-Derived Selenium Diiodide with Silver Tetrafluoroborate Isolation of Iodonium Ion Complexes with Selones
 
Creator MANJARE, ST
SINGH, HB
BUTCHER, RJ
 
Subject Iodine
Tellurium
Carbenes
Selenium
RAY CRYSTAL-STRUCTURES
HYPERVALENT IODINE
STRUCTURAL-CHARACTERIZATION
HETEROCYCLIC THIOAMIDES
MOLECULAR-STRUCTURE
ANTITHYROID DRUGS
CHARGE-TRANSFER
FT-RAMAN
ADDUCTS
SALTS
 
Description The oxidation reactions of diiodoselones 10a and 10b with silver tetrafluoroborate afford linear complexes of iodonium ions with selones 13a and 13b. The decomposition of the tellurium tetraiodide adduct with benzimidazolin-2-selone (12) in chloroform also affords a similar iodonium ion complex 13c. Crystal structure analysis of 13a13c shows interesting supramolecular formation by CHF, CHBr, CHI, Se, and I interactions.
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2014-10-15T16:41:42Z
2014-10-15T16:41:42Z
2013
 
Type Article
 
Identifier EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (12)2161-2166
http://dx.doi.org/10.1002/ejic.201201238
http://dspace.library.iitb.ac.in/jspui/handle/100/15236
 
Language en