Oxidation of Carbene-Derived Selenium Diiodide with Silver Tetrafluoroborate Isolation of Iodonium Ion Complexes with Selones
DSpace at IIT Bombay
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Title |
Oxidation of Carbene-Derived Selenium Diiodide with Silver Tetrafluoroborate Isolation of Iodonium Ion Complexes with Selones
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Creator |
MANJARE, ST
SINGH, HB BUTCHER, RJ |
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Subject |
Iodine
Tellurium Carbenes Selenium RAY CRYSTAL-STRUCTURES HYPERVALENT IODINE STRUCTURAL-CHARACTERIZATION HETEROCYCLIC THIOAMIDES MOLECULAR-STRUCTURE ANTITHYROID DRUGS CHARGE-TRANSFER FT-RAMAN ADDUCTS SALTS |
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Description |
The oxidation reactions of diiodoselones 10a and 10b with silver tetrafluoroborate afford linear complexes of iodonium ions with selones 13a and 13b. The decomposition of the tellurium tetraiodide adduct with benzimidazolin-2-selone (12) in chloroform also affords a similar iodonium ion complex 13c. Crystal structure analysis of 13a13c shows interesting supramolecular formation by CHF, CHBr, CHI, Se, and I interactions.
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Publisher |
WILEY-V C H VERLAG GMBH
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Date |
2014-10-15T16:41:42Z
2014-10-15T16:41:42Z 2013 |
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Type |
Article
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Identifier |
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (12)2161-2166
http://dx.doi.org/10.1002/ejic.201201238 http://dspace.library.iitb.ac.in/jspui/handle/100/15236 |
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Language |
en
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