Record Details

Efficient and Stereoselective Nitration of Mono- and Disubstituted Olefins with AgNO2 and TEMPO

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Efficient and Stereoselective Nitration of Mono- and Disubstituted Olefins with AgNO2 and TEMPO
 
Creator MAITY, S
MANNA, S
RANA, S
NAVEEN, T
MALLICK, A
MAITI, D
 
Subject ORGANIC-SYNTHESIS
MICHAEL ADDITION
NITROALKENES
NITROOLEFINS
CATALYSIS
HYDROGENATION
CONVENIENT
NITROXIDES
CHEMISTRY
STYRENES
 
Description Nitroolefin is a common and versatile reagent. Its synthesis from olefin is generally limited by the formation of mixture of cis and trans compounds. Here we report that silver nitrite (AgNO2) along with TEMPO can promote the regio- and stereoselective nitration of a broad range of olefins. This work discloses a new and efficient approach wherein starting from olefin, nitroalkane radical formation and subsequent transformations lead to the desired nitroolefin in a stereoselective manner.
 
Publisher AMER CHEMICAL SOC
 
Date 2014-10-15T17:03:15Z
2014-10-15T17:03:15Z
2013
 
Type Article
 
Identifier JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(9)3355-3358
http://dx.doi.org/10.1021/ja311942e
http://dspace.library.iitb.ac.in/jspui/handle/100/15279
 
Language en