Record Details

Rauhut-Currier Reaction of Nitroalkenes with Vinyl Sulfones

DSpace at IIT Bombay

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Title Rauhut-Currier Reaction of Nitroalkenes with Vinyl Sulfones
 
Creator KUMAR, R
KUMAR, T
MOBIN, SM
NAMBOTHIRI, INN
 
Subject BAYLIS-HILLMAN REACTION
DABCO-CATALYZED DIMERIZATION
CONJUGATED NITROALKENES
ANTICANCER ACTIVITY
ACTIVATED ALKENES
ACRYLIC COMPOUNDS
ESTERS
KETONES
HYDROXYALKYLATION
1,4-PENTADIENES
 
Description The Rauhut-Currier reaction between nitroalkenes and vinyl sulfones has been successfully carried out for the first time. The reaction proceeds in the presence of an imidazole/LiCl catalyst system in dioxane to provide the adducts possessing a synthetically useful 1-bis-sulfonyl-3-nitroalkene moiety in good to excellent yield. A one-pot transformation of the products to beta-sulfonyl-alpha,beta-unsaturated ketoximes has also been demonstrated.
 
Publisher AMER CHEMICAL SOC
 
Date 2014-10-16T05:38:36Z
2014-10-16T05:38:36Z
2013
 
Type Article
 
Identifier JOURNAL OF ORGANIC CHEMISTRY, 78(10)5073-5077
http://dx.doi.org/10.1021/jo400528j
http://dspace.library.iitb.ac.in/jspui/handle/100/15357
 
Language en