Rauhut-Currier Reaction of Nitroalkenes with Vinyl Sulfones
DSpace at IIT Bombay
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Title |
Rauhut-Currier Reaction of Nitroalkenes with Vinyl Sulfones
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Creator |
KUMAR, R
KUMAR, T MOBIN, SM NAMBOTHIRI, INN |
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Subject |
BAYLIS-HILLMAN REACTION
DABCO-CATALYZED DIMERIZATION CONJUGATED NITROALKENES ANTICANCER ACTIVITY ACTIVATED ALKENES ACRYLIC COMPOUNDS ESTERS KETONES HYDROXYALKYLATION 1,4-PENTADIENES |
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Description |
The Rauhut-Currier reaction between nitroalkenes and vinyl sulfones has been successfully carried out for the first time. The reaction proceeds in the presence of an imidazole/LiCl catalyst system in dioxane to provide the adducts possessing a synthetically useful 1-bis-sulfonyl-3-nitroalkene moiety in good to excellent yield. A one-pot transformation of the products to beta-sulfonyl-alpha,beta-unsaturated ketoximes has also been demonstrated.
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Publisher |
AMER CHEMICAL SOC
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Date |
2014-10-16T05:38:36Z
2014-10-16T05:38:36Z 2013 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANIC CHEMISTRY, 78(10)5073-5077
http://dx.doi.org/10.1021/jo400528j http://dspace.library.iitb.ac.in/jspui/handle/100/15357 |
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Language |
en
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