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Morita-Baylis-Hillman and Rauhut-Currier Reactions of Conjugated Nitroalkenes

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Title Morita-Baylis-Hillman and Rauhut-Currier Reactions of Conjugated Nitroalkenes
 
Creator KAUR, K
NAMBOOTHIRI, INN
 
Subject DMAP
Imidazole
Morita-Baylis-Hillman reaction
Nitroalkenes
Rauhut-Currier reaction
INTRAMOLECULAR MICHAEL ADDITION
BASE-MEDIATED REACTION
NITROALLYLIC ACETATES
ANTICANCER ACTIVITY
KINETIC RESOLUTION
REGIOSELECTIVE SYNTHESIS
ADDUCTS
ORGANOCATALYSTS
CHEMISTRY
ALDEHYDES
 
Description alpha-Functionalization of conjugated nitroalkenes and nitrodienes using various electrophiles in the presence of amine catalysts such as imidazole and DMAP and the synthetic applications of the products are reviewed. The electrophiles include formaldehyde, activated non-enolizable carbonyl compounds, activated imines, azodicarboxylates as well as activated alkenes such as nitroalkenes, MVK and acrylate. Reports on synthetic applications of the products, though only appearing in the last three years, highlight the potential of these multi-functional scaffolds to take part in diverse transformations such as Michael addition, cycloaddition and many cascade reactions leading to complex molecules including natural products.
 
Publisher SWISS CHEMICAL SOC
 
Date 2014-10-16T06:48:10Z
2014-10-16T06:48:10Z
2012
 
Type Article
 
Identifier CHIMIA, 66(12)913-920
http://dx.doi.org/10.2533/chimia.2012.913
http://dspace.library.iitb.ac.in/jspui/handle/100/15473
 
Language en