Stereoselective Synthesis of Substituted 1,4-Oxazepanes by Intramolecular Reductive Etherification
DSpace at IIT Bombay
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Title |
Stereoselective Synthesis of Substituted 1,4-Oxazepanes by Intramolecular Reductive Etherification
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Creator |
GHARPURE, SJ
PRASAD, JVK |
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Subject |
Heterocycles
Reductive etherification Lewis acids Diastereoselectivity VINYLOGOUS CARBONATES FUNCTIONALIZED MORPHOLINES RING-SYSTEM DERIVATIVES CONSTRUCTION BATRACHOTOXIN CYCLIZATION OXAZEPANES MODEL ACID |
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Description |
A facile and general strategy is developed for the stereoselective synthesis of substituted 1,4-oxazepane derivatives through an intramolecular reductive etherification reaction. The effects of the substituents present on the oxonium ion and the position of this ion with respect to the nitrogen atom on the yield and selectivity of the reaction are also studied.
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Publisher |
WILEY-V C H VERLAG GMBH
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Date |
2014-10-16T13:45:38Z
2014-10-16T13:45:38Z 2013 |
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Type |
Article
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Identifier |
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (11)2076-2079
http://dx.doi.org/10.1002/ejoc.201300135 http://dspace.library.iitb.ac.in/jspui/handle/100/15700 |
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Language |
en
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