Record Details

Development of the First Menthane-Based Chiral Bis(p-allylpalladium) Catalysis: Asymmetric Allylation of Imines

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Development of the First Menthane-Based Chiral Bis(p-allylpalladium) Catalysis: Asymmetric Allylation of Imines
 
Creator FERNANDES, RA
CHAUDHARI, DA
 
Subject Asymmetric catalysis
Homogeneous catalysis
C-C coupling
Allyl-ation
Palladium
Enantioselectivity
PI-ALLYLPALLADIUM COMPLEX
HIGHLY STEREOSELECTIVE-SYNTHESIS
HOMOALLYLIC AMINES
ENANTIOSELECTIVE ALLYLATION
ORGANOMETALLIC REAGENTS
N-ACYLHYDRAZONES
METAL-COMPOUNDS
PALLADIUM
ALLYLTRICHLOROSILANES
BUTADIENE
 
Description A new ethylidene menthane-based chiral p-allylpalladium complex catalyzes the asymmetric allylation of various imines with allyltributylstannane and 1 equiv. of water to give chiral homoallylamines in good yields and enantioselectivities. The reaction was carried out essentially under neutral conditions and displayed a good transfer of chiral information from the menthane skeleton through the formation of a bis(p-allylpalladium) species. This is the first example of menthane-based chiral bis(p-allylpalladium) catalysis.
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2014-10-16T14:08:51Z
2014-10-16T14:08:51Z
2012
 
Type Article
 
Identifier EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (10)1945-1952
http://dx.doi.org/10.1002/ejoc.201101588
http://dspace.library.iitb.ac.in/jspui/handle/100/15746
 
Language en