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Synthesis, characterization and ion recognition studies of lower rim 1,3-di{rhodamine} conjugate of calix[4]arene

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Title Synthesis, characterization and ion recognition studies of lower rim 1,3-di{rhodamine} conjugate of calix[4]arene
 
Creator CHINTA, JP
DESSINGOU, J
RAO, CP
 
Subject Rhodamine conjugate of calix[4]arene
ratiometric sensor for Hg2+
ion recognition
emission and absorption titrations
SELECTIVE FLUORESCENT CHEMOSENSOR
RHODAMINE
SENSOR
HG2+
WATER
FE3+
CR3+
PB2+
 
Description An amido-linked rhodamine conjugate of calix[4]arene, L has been synthesized and characterized. Metal ion recognition properties of L have been studied by emission and absorption techniques with 14 different metal ions including the transition ones. Results show that, L exhibits ratiometric emission intensity towards Hg2+, Fe2+, Fe3+, Cu2+, Pb2+ and Zn2+. Composition of the complex formed in the solution has been found to be 1:2 (L:Mn+), based on the Job's plot. The L can also act as a chemosensor for Hg2+ through naked eye detection. Fluorescence quenching observed at 485 nm follows an order, Hg2+ >> Fe3+ similar to Cu2+ > Zn2+ > Pb2+ > Ca2+, while the enhancement observed at 580 nm follows, Hg2+ >> Fe2+ similar to Pb2+ > Zn2+. Mode of interaction of Mn+ with L is by the ring opening of spirolactam moiety.
 
Publisher INDIAN ACAD SCIENCES
 
Date 2014-10-16T15:21:09Z
2014-10-16T15:21:09Z
2013
 
Type Article
 
Identifier JOURNAL OF CHEMICAL SCIENCES, 125(6)1455-1461
0974-3626
0973-7103
http://dspace.library.iitb.ac.in/jspui/handle/100/15889
 
Language en