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Application of bisphosphomide-palladium(II) pincer complex in Suzuki-Miyaura cross-coupling reaction under microwave irradiation

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Title Application of bisphosphomide-palladium(II) pincer complex in Suzuki-Miyaura cross-coupling reaction under microwave irradiation
 
Creator KUMARAVEL, M
KUMAR, P
BALAKRISHNA, MS
 
Subject Pincer complex
bisphosphomide
Suzuki-Miyaura coupling
microwave irradiation
palladium(II)
TRANSITION-METAL CHEMISTRY
CATALYTIC INVESTIGATIONS
COORDINATION BEHAVIOR
DFT CALCULATIONS
LIGANDS
PHOSPHINES
GROUP-10
 
Description The bisphosphomide-based pincer complex [PdBr{2,6-{ Ph2PC(O)}(2)(C6H3)}] (2) has shown very high catalytic activity in Suzuki-Miyaura cross coupling reaction under microwave irradiation for a variety of aryl bromides and aryl boronic acids. The complex showed the same efficiency for gram scale reactions.
 
Publisher INDIAN ACAD SCIENCES
 
Date 2014-12-28T08:56:56Z
2014-12-28T08:56:56Z
2014
 
Type Article
 
Identifier JOURNAL OF CHEMICAL SCIENCES, 126(3)711-716
0974-3626
0973-7103
http://dx.doi.org/10.1007/s12039-014-0594-z
http://dspace.library.iitb.ac.in/jspui/handle/100/16237
 
Language English