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Correlation between carbon-carbon bond length and the ease of retro Diels-Alder reaction

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Title Correlation between carbon-carbon bond length and the ease of retro Diels-Alder reaction
 
Creator KOTHA, S
BANERJEE, S
SHAIKH, M
 
Subject Crystal structures
retro Diels-Alder reaction
spirocyclic dienes
 
Description The bond length between C8-C9 in (1(') R,4(') S,4a(') R,8a(') S)-6('),7(')-dimethyl-1('),4('),4a('),8a(')-tetrahydrospiro [cyclopropane-1,9(')-[1,4]methanonaphthalene]-5('),8(')-dione is 1.571 (2) and between C7-C12 is 1.567 (2) which are longer than the corresponding bond length for saturated bicyclic systems (1.531-1.535 ). This paper reports the correlation between bond length and the ease of retro Diels -Alder reaction.
 
Publisher INDIAN ACAD SCIENCES
 
Date 2014-12-28T08:58:58Z
2014-12-28T08:58:58Z
2014
 
Type Article
 
Identifier JOURNAL OF CHEMICAL SCIENCES, 126(5)1369-1371
0974-3626
0973-7103
http://dx.doi.org/10.1007/s12039-014-0709-6
http://dspace.library.iitb.ac.in/jspui/handle/100/16241
 
Language English