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Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu4X4 clusters as nodes

DSpace at IIT Bombay

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Title Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu4X4 clusters as nodes
 
Creator SIDDIQUI, MM
MOBIN, SM
SENKOVSKA, I
KASKEL, S
BALAKRISHNA, MS
 
Subject METAL-ORGANIC FRAMEWORK
ZEOLITIC IMIDAZOLATE FRAMEWORKS
POROUS COORDINATION POLYMERS
REVERSIBLE CONVERSION
COMPLEXES
REDOX
MACROCYCLE
CHEMISTRY
LIGANDS
FAMILY
 
Description Two novel cyclodiphosphazane cluster frameworks with Cu4X4 clusters as tetrahedral nodes and ferrocenyl cyclodiphosphazanes [Fe(n(5)-C5H4)(2)((PNBu)-Bu-t)(2)] as ditopic linkers have been synthesized. These frameworks having sodalite topology display a unique integration of porosity and redox activity and offer new opportunities for the synthesis of zeotype frameworks with soft phosphorus-based ligands.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2014-12-28T11:37:28Z
2014-12-28T11:37:28Z
2014
 
Type Article
 
Identifier CHEMICAL COMMUNICATIONS, 50(82)12273-12276
1359-7345
1364-548X
http://dx.doi.org/10.1039/c4cc03810j
http://dspace.library.iitb.ac.in/jspui/handle/100/16377
 
Language English