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Efficient and Stereoselective Nitration of Olefins with AgNO2 and TEMPO

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Field Value
 
Title Efficient and Stereoselective Nitration of Olefins with AgNO2 and TEMPO
 
Creator MAITY, S
NAVEEN, T
SHARMA, U
MAITI, D
 
Subject high yields
nitroolefin
stereoselective
nitration
olefin
NITROALKENES
NITROOLEFINS
CONVENIENT
 
Description Synthetic utility of nitroolefins in fundamental organic synthesis has inspired us to develop a method to access nitroolefins stereoselectively starting from olefins. Silver nitrite along with catalytic TEMPO was found to be the reagent combination of choice. The method enjoys a broad scope and functional-group tolerance while nitroolefins are obtained in high yields with excellent E-selectivity.
 
Publisher GEORG THIEME VERLAG KG
 
Date 2014-12-28T11:55:01Z
2014-12-28T11:55:01Z
2014
 
Type Article
 
Identifier SYNLETT, 25(5)603-607
0936-5214
1437-2096
http://dx.doi.org/10.1055/s-0033-1340467
http://dspace.library.iitb.ac.in/jspui/handle/100/16412
 
Language English