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The mechanism of the NHC catalyzed aza-Morita-Baylis-Hillman reaction: insights into a new substrate-catalyzed bimolecular pathway

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Title The mechanism of the NHC catalyzed aza-Morita-Baylis-Hillman reaction: insights into a new substrate-catalyzed bimolecular pathway
 
Creator VERMA, P
VERMA, P
SUNOJ, RB
 
Subject N-HETEROCYCLIC CARBENE
ENANTIOSELECTIVITY
ORGANOCATALYSTS
CHEMISTRY
 
Description The first mechanistic study on the NHC-catalyzed aza-MBH reaction between cyclopentenone and N-mesylbenzaldimine using density functional theory reveals that a bimolecular mechanism, involving two molecules of benzaldimine in the proton transfer, is energetically more preferred over the conventional direct proton transfer.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2014-12-28T12:07:09Z
2014-12-28T12:07:09Z
2014
 
Type Article
 
Identifier ORGANIC & BIOMOLECULAR CHEMISTRY, 12(14)2176-2179
1477-0520
1477-0539
http://dx.doi.org/10.1039/c3ob42273a
http://dspace.library.iitb.ac.in/jspui/handle/100/16441
 
Language English