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Iron catalysed nitrosation of olefins to oximes

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Title Iron catalysed nitrosation of olefins to oximes
 
Creator RAY, R
CHOWDHURY, AD
MAITI, D
LAHIRI, GK
 
Subject BECKMANN REARRANGEMENT
CYCLOHEXANONE OXIME
SODIUM-BOROHYDRIDE
NITRIC-OXIDE
REGIOSELECTIVE SYNTHESIS
STYRENE DERIVATIVES
COBALT(II) COMPLEX
HYDROGEN-PEROXIDE
IONIC LIQUIDS
BUTYL NITRITE
 
Description Fe(BF4)(2.)6H(2)O/2,6-pyridinedicarboxylic acid catalysed nitrosation of a wide variety of substituted styrenes has been developed in the presence of t-BuONO/NaBH4 under H-2 pressure (10 bar) in MeOH-H2O (5 : 1) to afford corresponding oximes in good to excellent yields.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2014-12-28T12:12:39Z
2014-12-28T12:12:39Z
2014
 
Type Article
 
Identifier DALTON TRANSACTIONS, 43(1)38-41
1477-9226
1477-9234
http://dx.doi.org/10.1039/c3dt51764k
http://dspace.library.iitb.ac.in/jspui/handle/100/16462
 
Language English