Synthesis, structure and reactivity of [o-( 2,6-diisopropylphenyliminomethinyl)phenyl]selenenyl selenocyanate (RSeSeCN) and related derivatives
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Title |
Synthesis, structure and reactivity of [o-( 2,6-diisopropylphenyliminomethinyl)phenyl]selenenyl selenocyanate (RSeSeCN) and related derivatives
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Creator |
RAKESH, P
SINGH, HB JASINSKI, JP GOLEN, JA |
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Subject |
CENTER-DOT-N
CARBONYL BENZENESELENENYL DERIVATIVES GLUTATHIONE-PEROXIDASE ACTIVITY SE-77 NMR-SPECTROSCOPY ANTIOXIDANT ACTIVITY ORGANOSELENIUM COMPOUNDS CRYSTAL-STRUCTURE MOLECULAR PRECURSORS THIN-FILMS SELENIUM |
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Description |
The synthesis and the first X-ray structural characterization of a selenenyl selenocyanate, [o-(2,6-diisopro-pylphenyliminomethinyl)phenyl]selenenyl selenocyanate (DiPhSeSeCN), with a stable Se-Se bond are described. The isolation of stable DiPhSeSeCN, both in the solid state and in solution, is facilitated by strong intramolecular Se center dot center dot center dot N interaction. The compound DiPhSeSeCN, an example of unsymmetrical diselenide, did not exhibit any glutathione peroxidase-like activity. The reaction of DiPhSeSeCN with thiophenol afforded (3H-benzo[c][1,2] diselenol-3-yl)(phenyl) sulfane.
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Publisher |
ROYAL SOC CHEMISTRY
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Date |
2014-12-28T12:17:12Z
2014-12-28T12:17:12Z 2014 |
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Type |
Article
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Identifier |
DALTON TRANSACTIONS, 43(25)9431-9437
1477-9226 1477-9234 http://dx.doi.org/10.1039/c4dt00157e http://dspace.library.iitb.ac.in/jspui/handle/100/16480 |
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Language |
English
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