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Are Ligand-Stabilized Carboxylic Acid Derivatives with Ge=Te Bonds Isolable?

DSpace at IIT Bombay

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Field Value
 
Title Are Ligand-Stabilized Carboxylic Acid Derivatives with Ge=Te Bonds Isolable?
 
Creator SIWATCH, RK
YADAV, D
MUKHERJEE, G
RAJARAMAN, G
NAGENDRAN, S
 
Subject NATURAL RESONANCE THEORY
MOIETY E
COMPLEXES
GERMANIUM
CHEMISTRY
SE
GERMYLENE
CARBENES
ANALOGS
HALIDES
 
Description The stability of ligand-stabilized carboxylic acid derivatives (such as esters, amides, anhydrides, and acid halides) with terminal Ge=Te bonds is highly questionable as there is no report on such compounds. Nevertheless, we are able to isolate germatelluroester [LGe(Te)Ot-Bu] (4), germatelluroamide [LGe(Te)N(SiMe3)(2)] (5), and germatelluroacid anhydride [LGe(Te)OGe(Te)L] (6) complexes (L = aminotroponiminate (ATI)) as stable species. Consequently, the synthetic details, structural characterization, and UV-vis spectroscopic and theoretical studies on them are reported for the first time.
 
Publisher AMER CHEMICAL SOC
 
Date 2014-12-28T12:28:08Z
2014-12-28T12:28:08Z
2014
 
Type Article
 
Identifier INORGANIC CHEMISTRY, 53(10)5073-5079
0020-1669
1520-510X
http://dx.doi.org/10.1021/ic500116f
http://dspace.library.iitb.ac.in/jspui/handle/100/16522
 
Language English