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Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [Mn-12(III)] Wheel

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Title Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [Mn-12(III)] Wheel
 
Creator SANZ, S
FROST, JM
RAJESHKUMAR, T
DALGARNO, SJ
RAJARAMAN, G
WERNSDORFER, W
SCHNACK, J
LUSBY, PJ
BRECHIN, EK
 
Subject density functional calculations
finite-temperature Lanczos method
manganese
molecular magnets
self-assembly
SINGLE-MOLECULE MAGNETS
SPIN GROUND-STATE
LANCZOS METHOD
LOOP STRUCTURE
MIXED-VALENT
SHAPED MN-12
SOLID-STATE
COMPLEXES
MANGANESE
SYSTEMS
 
Description Phenolic oxime and diethanolamine moieties have been combined into one organic framework, resulting in the formation of a novel ligand type that can be employed to construct a rare and unusual dodecametallic Mn wheel, within which nearest neighbours are coupled ferromagnetically.
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2014-12-28T12:41:31Z
2014-12-28T12:41:31Z
2014
 
Type Article
 
Identifier CHEMISTRY-A EUROPEAN JOURNAL, 20(11)3010-3013
0947-6539
1521-3765
http://dx.doi.org/10.1002/chem.201304740
http://dspace.library.iitb.ac.in/jspui/handle/100/16573
 
Language English