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A Domino Enyne/IMDA Approach to the Core Structure of (-) Vinigrol

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Title A Domino Enyne/IMDA Approach to the Core Structure of (-) Vinigrol
 
Creator BETKEKAR, VV
SAYYAD, AA
KALIAPPAN, KP
 
Subject CLOSING METATHESIS APPROACH
TRICYCLIC RING-SYSTEM
VIRGARIA-NIGRA
CONSTRUCTION
SKELETON
CYCLIZATION
REARRANGEMENT
FRAMEWORK
STRATEGY
CASCADE
 
Description We report here an enantioselective formal synthesis of vinigrol involving a 1-2-3 strategy: one pot and two reactions with the formation of three rings leading to the core structure of vinigrol from its stereochemically well-defined acyclic precursor.
 
Publisher AMER CHEMICAL SOC
 
Date 2014-12-28T12:55:07Z
2014-12-28T12:55:07Z
2014
 
Type Article
 
Identifier ORGANIC LETTERS, 16(21)5540-5543
1523-7060
1523-7052
http://dx.doi.org/10.1021/ol502497n
http://dspace.library.iitb.ac.in/jspui/handle/100/16622
 
Language English