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Experimental Determination of NH3 Solubility in Toluene at Pressures up to 340 kPa at 398 K

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Title Experimental Determination of NH3 Solubility in Toluene at Pressures up to 340 kPa at 398 K
 
Creator BHATTACHARYYA, SC
PANT, CS
MEHRA, A
BHATTACHARYA, B
MALIK, RK
 
Subject Solubility
1,3,5-Triamino-2,4,6-trinitrobenzene
Henry's law constant
Fugacity
Krichevsky-Kasarnovsky equation
ORGANIC-SOLVENTS
HYDROGEN
NITROGEN
WATER
 
Description The solubility of ammonia in toluene has been measured at 398 K and at pressures up to 340 kPa using a static, synthetic and isochoric technique. The goal of the present study is to determine the equilibrium solubility of ammonia in toluene at a pressure and temperature regime that is relevant to the reaction conditions of amination of 1,3,5-trichloro-2,4,6-trinitrobenzene leading to the formation of 1,3,5-triamino-2,4,6-trinitro benzene. The ammonia solubility data in toluene were hitherto unavailable under these experimental conditions. The solubility data have also been compared with the result obtained from a direct sampling method. The results are in agreement with Krichevsky-Kasarnovsky equation. The Henry's law constant at the reaction temperature has been determined.
 
Publisher SPRINGER/PLENUM PUBLISHERS
 
Date 2014-12-28T14:31:50Z
2014-12-28T14:31:50Z
2014
 
Type Article
 
Identifier JOURNAL OF SOLUTION CHEMISTRY, 43(8)1466-1475
0095-9782
1572-8927
http://dx.doi.org/10.1007/s10953-014-0215-y
http://dspace.library.iitb.ac.in/jspui/handle/100/16760
 
Language English