Generation of Arylated Quinones by Iron-Catalyzed Oxidative Arylation of Phenols: Formal Synthesis of Phellodonin, Sarcodonin e, Leucomelone and Betulinan A
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Title |
Generation of Arylated Quinones by Iron-Catalyzed Oxidative Arylation of Phenols: Formal Synthesis of Phellodonin, Sarcodonin e, Leucomelone and Betulinan A
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Creator |
DEB, A
AGASTI, S SABOO, T MAITI, D |
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Subject |
arylated quinones
arylation iron catalysis natural products phenols DIAZOTISED ANTHRANILIC ACID ARYLBORONIC ACIDS AROMATIC-COMPOUNDS COUPLING REACTIONS AEROBIC OXIDATION ALKYL-HALIDES IONIC LIQUID NITRATION CHLORIDE 1,4-BENZOQUINONES |
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Description |
Biologically and pharmaceutically relevant arylated quinones (Quin-Ar) have been synthesized via direct CH arylation of a variety of phenols using arylboronic acids. An inexpensive, environmentally friendly iron catalyst, ferric sulphate, Fe-2(SO4)(3), was employed in this operationally simple and efficient method.
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Publisher |
WILEY-V C H VERLAG GMBH
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Date |
2014-12-28T14:44:52Z
2014-12-28T14:44:52Z 2014 |
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Type |
Article
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Identifier |
ADVANCED SYNTHESIS & CATALYSIS, 356(4)705-710
1615-4150 1615-4169 http://dx.doi.org/10.1002/adsc.201301084 http://dspace.library.iitb.ac.in/jspui/handle/100/16786 |
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Language |
English
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