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Generation of Arylated Quinones by Iron-Catalyzed Oxidative Arylation of Phenols: Formal Synthesis of Phellodonin, Sarcodonin e, Leucomelone and Betulinan A

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Title Generation of Arylated Quinones by Iron-Catalyzed Oxidative Arylation of Phenols: Formal Synthesis of Phellodonin, Sarcodonin e, Leucomelone and Betulinan A
 
Creator DEB, A
AGASTI, S
SABOO, T
MAITI, D
 
Subject arylated quinones
arylation
iron catalysis
natural products
phenols
DIAZOTISED ANTHRANILIC ACID
ARYLBORONIC ACIDS
AROMATIC-COMPOUNDS
COUPLING REACTIONS
AEROBIC OXIDATION
ALKYL-HALIDES
IONIC LIQUID
NITRATION
CHLORIDE
1,4-BENZOQUINONES
 
Description Biologically and pharmaceutically relevant arylated quinones (Quin-Ar) have been synthesized via direct CH arylation of a variety of phenols using arylboronic acids. An inexpensive, environmentally friendly iron catalyst, ferric sulphate, Fe-2(SO4)(3), was employed in this operationally simple and efficient method.
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2014-12-28T14:44:52Z
2014-12-28T14:44:52Z
2014
 
Type Article
 
Identifier ADVANCED SYNTHESIS & CATALYSIS, 356(4)705-710
1615-4150
1615-4169
http://dx.doi.org/10.1002/adsc.201301084
http://dspace.library.iitb.ac.in/jspui/handle/100/16786
 
Language English