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DIVERISITY ORIENTED APPROACH TO SPIROBARBITURIC ACID DERIVATIVES VIA A [2+2+2] CYCLOADDITION AND DIELS-ALDER REACTION AS KEY STEPS

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Title DIVERISITY ORIENTED APPROACH TO SPIROBARBITURIC ACID DERIVATIVES VIA A [2+2+2] CYCLOADDITION AND DIELS-ALDER REACTION AS KEY STEPS
 
Creator KOTHA, S
ALI, R
 
Subject Spirocyclic Compound
Rongalite
1,3-Dimethylbarbituric Acid
[2+2+2] Cycloaddition Reaction
Diels-Alder Reaction
RING-CLOSING METATHESIS
BARBITURIC-ACID
FREDERICAMYCIN-A
STEREOCONTROLLED SYNTHESIS
MOLECULAR FRAMEWORKS
ORGANIC-SYNTHESIS
ENYNE METATHESIS
TIC DERIVATIVES
SPIRO
DIVERSITY
 
Description Spirobarbituric acid derivatives are assembled via a [2+2+2] cycloaddition and the Diels-Alder (DA) reaction as key steps. A transient diene 13 containing spiribarbituric acid suitable for DA reaction has been generated in situ from the sultine derivative 12, which in turn was obtained by the usage of rongalite.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2014-12-28T18:04:01Z
2014-12-28T18:04:01Z
2014
 
Type Article
 
Identifier HETEROCYCLES, 88(1)789-797
0385-5414
1881-0942
http://dx.doi.org/10.3987/COM-13-S(S)48
http://dspace.library.iitb.ac.in/jspui/handle/100/17060
 
Language English