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Crystal Structures of the Complexes of Zn(II), Cd(II), and Hg(II) with 1,2,5-Selenadiazolopyridine: Ligation of N vs Se ?

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Title Crystal Structures of the Complexes of Zn(II), Cd(II), and Hg(II) with 1,2,5-Selenadiazolopyridine: Ligation of N vs Se ?
 
Creator SINGH, P
SHARMA, S
SINGH, HB
BUTCHER, RJ
 
Subject 1,2,5-Selenadiazolopyridine
Supramolecular framework
Benzoselenadiazole
Selenophilicity
Soft metal ions
METHYLMERCURY TOXICITY
MERCURY
2,1,3-BENZOSELENADIAZOLE
SELENIUM
ASSOCIATION
CHEMISTRY
RADICALS
1,2,5-CHALCOGENADIAZOLES
2,1,3-BENZOTHIADIAZOLE
SPECTROSCOPY
 
Description The coordination ability of 1, 2, 5-selenadiazolopyridine (psd) towards MCl2 (M = Zn, Cd, Hg), and HgBr2 has been investigated. The 2:1 reactions of psd with MCl2 and HgBr2 afforded dimeric [(psd)(2)ZnCl2](2), polymeric [(psd)(2)CdCl2] n and monomeric (psd)(2)HgBr2 complexes. The 1:1 reactions of psd with HgX2 (X = Cl, Br), gave only polymeric complexes i.e. [(psd) HgX2](n). Single crystal X-ray diffraction studies of the complexes reveal that psd ligand coordinates to the metal ions either through azole N or pyridine N. In no case, coordination through the selenium donor was observed. These observations are also supported by DFT calculations. Complex [(psd)(2)CdCl2](n) is a 3D supramolecular framework extended by Cl -> Cd dative bond, Se center dot center dot center dot N-py secondary bonding and C-H center dot center dot center dot Cl hydrogen bonding interactions.
 
Publisher NATL ACAD SCIENCES INDIA
 
Date 2014-12-29T04:56:19Z
2014-12-29T04:56:19Z
2014
 
Type Article
 
Identifier PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES INDIA SECTION A-PHYSICAL SCIENCES, 84(2)269-280
0369-8203
2250-1762
http://dx.doi.org/10.1007/s40010-014-0146-4
http://dspace.library.iitb.ac.in/jspui/handle/100/17131
 
Language English