Record Details

Chalcogenide derivatives of 1,2,5-triphenyl-1H-phosphole: structure and photophysical properties

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Chalcogenide derivatives of 1,2,5-triphenyl-1H-phosphole: structure and photophysical properties
 
Creator KUMARAVEL, M
MAGUE, JT
BALAKRISHNA, MS
 
Subject Phospholes
Chalcogenide derivatives
Photophysical properties
Fluorescence quenching
PI-CONJUGATED SYSTEMS
ORGANIC-CHEMISTRY
DFT CALCULATIONS
LIGANDS
COORDINATION
PHOSPHOLES
COMPLEXES
OC6H4OME-O
OLIGOMERS
BEHAVIOR
 
Description Chalcogenide derivatives of triphenylphosphole (oxide (1), sulfide (2) and selenide (3)) were synthesized and characterized by X-ray diffraction studies. Intermolecular interactions were observed in the bulk molecular packing in terms of hydrogen bonding for 1 or pi-pi stacking for 3. One of the useful applications of the chalcogenide derivatives of triphenylphosphole has been demonstrated utilizing the photophysical properties of 1 to detect aromatic nitro compounds through fluorescence quenching. (C) 2014 Elsevier Ltd. All rights reserved.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2014-12-29T05:22:32Z
2014-12-29T05:22:32Z
2014
 
Type Article
 
Identifier TETRAHEDRON LETTERS, 55(18)2957-2961
0040-4039
http://dx.doi.org/10.1016/j.tetlet.2014.03.102
http://dspace.library.iitb.ac.in/jspui/handle/100/17182
 
Language English