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Cycloaddition of cyclohexa-2,4-dienones with beta-nitroacrylates: a short and efficient entry into bicyclo[2.2.2]octanes endowed with a-nitro-ester and a-amino ester functionality

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Title Cycloaddition of cyclohexa-2,4-dienones with beta-nitroacrylates: a short and efficient entry into bicyclo[2.2.2]octanes endowed with a-nitro-ester and a-amino ester functionality
 
Creator BEHERA, TK
ISLAM, SN
MOBIN, SM
SINGH, V
 
Subject Cycloaddition
Cyclohexa-2,4-dienones
beta-Nitroacrylate
Diels-Alder reaction
beta-Aminoester
ENANTIOSELECTIVE SYNTHESIS
STEREOSELECTIVE ROUTE
PERIODATE OXIDATION
TURN INDUCER
ALPHA-AMINO
ACIDS
PEPTIDES
ANALOGS
DERIVATIVES
ENANTIOPURE
 
Description Regio- and stereoselective cycloaddition of beta-nitroacrylates with electron deficient cyclohexa-2,4-dienones leading to highly functionalised bicyclo[2.2.2]octanes having the beta-nitroester group and their transformation to bicyclo[2.2.2]octanes having beta-aminoester functionality is described. (C) 2014 Elsevier Ltd. All rights reserved.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2014-12-29T05:24:03Z
2014-12-29T05:24:03Z
2014
 
Type Article
 
Identifier TETRAHEDRON LETTERS, 55(37)5170-5173
0040-4039
http://dx.doi.org/10.1016/j.tetlet.2014.07.097
http://dspace.library.iitb.ac.in/jspui/handle/100/17185
 
Language English