Record Details

An efficient approach for the synthesis of functionalized selenoethers and selenacalix[4]thiophenes, {2,5-(mu-Se)(3,4-dialkoxythiophene)}(4)

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title An efficient approach for the synthesis of functionalized selenoethers and selenacalix[4]thiophenes, {2,5-(mu-Se)(3,4-dialkoxythiophene)}(4)
 
Creator KUMAR, P
KASHID, VS
MAGUE, JT
BALAKRISHNA, MS
 
Subject Selenoethers
Selenacalix[4]thiophenes
Selenamacrocycles
Selenacalixarenes
TRANSITION-METAL-COMPLEXES
ORGANOSELENIUM COMPOUNDS
CONFORMATIONAL-ANALYSIS
CALIXARENE FAMILY
SELENIUM
LIGANDS
THIACALIXARENES
CARCINOGENESIS
THIOETHERS
CHEMISTRY
 
Description An efficient method for the synthesis of selenoethers and selenacalix[4]thiophene utilizing SeCl2 is described. Reactions of phenols with SeCl2 produce the corresponding selenoethers in moderate to good yields. The selenacalix[4]thiophenes, [-Se-3,4-(C-4(OR)(2)S)](4) (R = CH3, C6H13) were synthesized by convenient one-pot electrophilic aromatic substitution reaction of dialkoxy thiophene with SeCl2 in good yield. (C) 2014 Elsevier Ltd. All rights reserved.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2014-12-29T05:24:34Z
2014-12-29T05:24:34Z
2014
 
Type Article
 
Identifier TETRAHEDRON LETTERS, 55(38)5232-5235
0040-4039
http://dx.doi.org/10.1016/j.tetlet.2014.08.005
http://dspace.library.iitb.ac.in/jspui/handle/100/17186
 
Language English