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Non-innocent Additives in a Palladium(II)-Catalyzed C-H Bond Activation Reaction: Insights into Multimetallic Active Catalysts

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Title Non-innocent Additives in a Palladium(II)-Catalyzed C-H Bond Activation Reaction: Insights into Multimetallic Active Catalysts
 
Creator ANAND, M
SUNOJ, RB
SCHAEFER, HF
 
Subject DINUCLEAR PALLADIUM COMPLEXES
CARBON-HYDROGEN BONDS
MILD CONDITIONS
MECHANISM
FUNCTIONALIZATION
ACETATE
ARENES
ALKYLATION
AMINATION
ARYLATION
 
Description The role of a widely employed additive (AgOAc) in a palladium acetate-catalyzed ortho-C-H bond activation reaction has been examined using the M06 density functional theory. A new hetero-bimetallic Pd-(mu-OAc)(3)-Ag is identified as the most likely active species. This finding could have far-reaching implications with respect to the notion of the active species in palladium catalysis in the presence of other metal salt additives.
 
Publisher AMER CHEMICAL SOC
 
Date 2014-12-29T05:42:50Z
2014-12-29T05:42:50Z
2014
 
Type Article
 
Identifier JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 136(15)5535-5538
0002-7863
http://dx.doi.org/10.1021/ja412770h
http://dspace.library.iitb.ac.in/jspui/handle/100/17222
 
Language English