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Iron(III) Sulfate as Terminal Oxidant in the Synthesis of Methyl Ketones via Wacker Oxidation

DSpace at IIT Bombay

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Field Value
 
Title Iron(III) Sulfate as Terminal Oxidant in the Synthesis of Methyl Ketones via Wacker Oxidation
 
Creator FERNANDES, RA
CHAUDHARI, DA
 
Subject SUPERCRITICAL CARBON-DIOXIDE
PALLADIUM-CATALYZED OXIDATION
AEROBIC OXIDATION
SELECTIVE OXIDATION
MOLECULAR-OXYGEN
REGIOSELECTIVE OXIDATION
ORGANIC-CHEMICALS
HYDROGEN-PEROXIDE
OLEFINS
ALKYNES
 
Description An efficient and environmentally benign method using Fe(III) sulfate as a terminal oxidant in the synthesis of methyl ketones from terminal olefins via the Wacker process is developed. The methodology offers high selectivity for a Markonikov product, shows good functional group compatibility, involves mild reaction conditions, and is operationally simple. Fe-2(SO4)(3) is the sole terminal oxidant in this process. The method holds potential for future applications in organic synthesis.
 
Publisher AMER CHEMICAL SOC
 
Date 2014-12-29T05:45:23Z
2014-12-29T05:45:23Z
2014
 
Type Article
 
Identifier JOURNAL OF ORGANIC CHEMISTRY, 79(12)5787-5793
0022-3263
http://dx.doi.org/10.1021/jo500921j
http://dspace.library.iitb.ac.in/jspui/handle/100/17227
 
Language English