Total syntheses of rubiginone A(2), C-2, and fujianmycin A
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
Total syntheses of rubiginone A(2), C-2, and fujianmycin A
|
|
Creator |
VANGA, DG
KALIAPPAN, KP |
|
Subject |
ENANTIOSELECTIVE TOTAL-SYNTHESIS
ANTIBIOTICS (+)-RUBIGINONE B-2 DIELS-ALDER REACTION ANGUCYCLINE ANTIBIOTICS URDAMYCINONE-B RACEMIC VINYLCYCLOHEXENES ABSOLUTE-CONFIGURATION ASYMMETRIC-SYNTHESIS EFFICIENT SYNTHESIS (+)-OCHROMYCINONE |
|
Description |
The total syntheses of rubiginone A(2), C-2 and fujianmycin A are described. The synthesis involves Diels-Alder/aromatization and photo chemical reactions as key steps to construct the tetracyclic frame of benz[a]anthraquinone skeleton. Sharpless epoxidation, a copper-catalyzed regioselective epoxide opening, and enyne metathesis reactions are utilized as the key steps for the synthesis of chiral vinylcyclohexene.
|
|
Publisher |
ROYAL SOC CHEMISTRY
|
|
Date |
2014-12-29T06:05:19Z
2014-12-29T06:05:19Z 2014 |
|
Type |
Article
|
|
Identifier |
RSC ADVANCES, 4(25)12716-12722
2046-2069 http://dx.doi.org/10.1039/c3ra47775d http://dspace.library.iitb.ac.in/jspui/handle/100/17266 |
|
Language |
English
|
|