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Total syntheses of rubiginone A(2), C-2, and fujianmycin A

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Title Total syntheses of rubiginone A(2), C-2, and fujianmycin A
 
Creator VANGA, DG
KALIAPPAN, KP
 
Subject ENANTIOSELECTIVE TOTAL-SYNTHESIS
ANTIBIOTICS (+)-RUBIGINONE B-2
DIELS-ALDER REACTION
ANGUCYCLINE ANTIBIOTICS
URDAMYCINONE-B
RACEMIC VINYLCYCLOHEXENES
ABSOLUTE-CONFIGURATION
ASYMMETRIC-SYNTHESIS
EFFICIENT SYNTHESIS
(+)-OCHROMYCINONE
 
Description The total syntheses of rubiginone A(2), C-2 and fujianmycin A are described. The synthesis involves Diels-Alder/aromatization and photo chemical reactions as key steps to construct the tetracyclic frame of benz[a]anthraquinone skeleton. Sharpless epoxidation, a copper-catalyzed regioselective epoxide opening, and enyne metathesis reactions are utilized as the key steps for the synthesis of chiral vinylcyclohexene.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2014-12-29T06:05:19Z
2014-12-29T06:05:19Z
2014
 
Type Article
 
Identifier RSC ADVANCES, 4(25)12716-12722
2046-2069
http://dx.doi.org/10.1039/c3ra47775d
http://dspace.library.iitb.ac.in/jspui/handle/100/17266
 
Language English