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Stereoselective inversion of gamma-vinyl-gamma-butyrolactone under palladium catalysis: application to the synthesis of (+)-exo- and (+)-endo-brevicomins

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Title Stereoselective inversion of gamma-vinyl-gamma-butyrolactone under palladium catalysis: application to the synthesis of (+)-exo- and (+)-endo-brevicomins
 
Creator FERNANDES, RA
KATTANGURU, P
BETHI, V
 
Subject WESTERN PINE BEETLE
ALLYLIC ALKYLATIONS
ENDO-BREVICOMIN
DERIVATIVES
ENANTIOMERS
ATTRACTANT
PHEROMONE
LACTONES
 
Description An efficient gamma-epimerization of gamma-vinyl-gamma-butyrolactone is studied under palladium catalysis. The building blocks derived there in are used in an efficient stereoselective synthesis of (+)-exo- and (+)-endo-brevicomins.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2014-12-29T06:07:55Z
2014-12-29T06:07:55Z
2014
 
Type Article
 
Identifier RSC ADVANCES, 4(28)14507-14512
2046-2069
http://dx.doi.org/10.1039/c4ra00814f
http://dspace.library.iitb.ac.in/jspui/handle/100/17271
 
Language English