Stereoselective inversion of gamma-vinyl-gamma-butyrolactone under palladium catalysis: application to the synthesis of (+)-exo- and (+)-endo-brevicomins
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Title |
Stereoselective inversion of gamma-vinyl-gamma-butyrolactone under palladium catalysis: application to the synthesis of (+)-exo- and (+)-endo-brevicomins
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Creator |
FERNANDES, RA
KATTANGURU, P BETHI, V |
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Subject |
WESTERN PINE BEETLE
ALLYLIC ALKYLATIONS ENDO-BREVICOMIN DERIVATIVES ENANTIOMERS ATTRACTANT PHEROMONE LACTONES |
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Description |
An efficient gamma-epimerization of gamma-vinyl-gamma-butyrolactone is studied under palladium catalysis. The building blocks derived there in are used in an efficient stereoselective synthesis of (+)-exo- and (+)-endo-brevicomins.
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Publisher |
ROYAL SOC CHEMISTRY
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Date |
2014-12-29T06:07:55Z
2014-12-29T06:07:55Z 2014 |
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Type |
Article
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Identifier |
RSC ADVANCES, 4(28)14507-14512
2046-2069 http://dx.doi.org/10.1039/c4ra00814f http://dspace.library.iitb.ac.in/jspui/handle/100/17271 |
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Language |
English
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