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Tandem Benzylic Oxidation/Dihydroxylation of alpha-Vinyl- and alpha-Alkenylbenzyl Alcohols

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Title Tandem Benzylic Oxidation/Dihydroxylation of alpha-Vinyl- and alpha-Alkenylbenzyl Alcohols
 
Creator FERNANDES, RA
KATTANGURU, P
 
Subject CATALYTIC ASYMMETRIC DIHYDROXYLATION
ALDOL REACTION
ALLYLIC ALCOHOLS
AMINOHYDROXYLATION
OXIDATION
COMPLEX
OLEFINS
KETONES
 
Description A de novo tandem benzylic oxidative dihydroxylation of alpha-vinyl- and alpha-alkenylbenzyl alcohols has been developed to give alpha,beta-dihydroxypropiophenones (= 2,3-dihydroxy-1-phenylpropan-1-ones) and alpha,beta-dihydroxyalkyl phenones. This method was shown to be substrate-selective and specific for the oxidation of benzylic alcohols.
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2016-01-14T10:40:25Z
2016-01-14T10:40:25Z
2015
 
Type Article
 
Identifier HELVETICA CHIMICA ACTA, 98(1)92-107
0018-019X
1522-2675
http://dx.doi.org/10.1002/hlca.201400143
http://dspace.library.iitb.ac.in/jspui/handle/100/17383
 
Language en