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Synthesis, characterization and DFT studies of 1, 1 '-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes

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Title Synthesis, characterization and DFT studies of 1, 1 '-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes
 
Creator KAUR-GHUMAAN, S
SREENITHYA, A
SUNOJ, RB
 
Subject ELECTROCHEMICAL PROTON REDUCTION
EFFECTIVE CORE POTENTIALS
IRON-SULFUR COMPLEXES
ACTIVE-SITE
ONLY HYDROGENASE
DESULFOVIBRIO-DESULFURICANS
STRUCTURAL-CHARACTERIZATION
CLOSTRIDIUM-PASTEURIANUM
MOLECULAR CALCULATIONS
BRIDGE
Bioinorganic chemistry
hydrogenase enzyme
bidentate phosphine
proton reduction
redox active ligands
density functional calculations
 
Description The reaction of [Fe-2(CO)(6)(mu-toluene-3, 4-benzenedithiolate)] 1 and bidentate diphosphine, 1, 1'-bis(diphenylphosphino)ferrocene (dppf) has been studied. New complexes obtained have been characterized by various spectroscopic techniques as bioinspired models of the iron hydrogenase active site. The crystal structure of [Fe-2(CO)(5)(kappa(1)-dppfO)(mu-toluene-3, 4-benzenedithiolate)] 4 is reported.
 
Publisher INDIAN ACAD SCIENCES
 
Date 2016-01-14T12:32:17Z
2016-01-14T12:32:17Z
2015
 
Type Article
 
Identifier JOURNAL OF CHEMICAL SCIENCES, 127(3)557-563
0974-3626
0973-7103
http://dx.doi.org/10.1007/s12039-015-0809-y
http://dspace.library.iitb.ac.in/jspui/handle/100/17505
 
Language en