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Reactivity of 1,2,3-triselena[3]ferrocenophane towards transition metal carbonyls

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Title Reactivity of 1,2,3-triselena[3]ferrocenophane towards transition metal carbonyls
 
Creator MATHUR, P
RAGHUVANSHI, A
MOBIN, SM
 
Subject FERROCENE-BASED UREAS
CRYSTAL-STRUCTURES
CHALCOGENIDE CLUSTERS
MOLECULAR-STRUCTURES
BRIDGING ATOMS
NITROGEN-RICH
COMPLEXES
SE
TE
MANGANESE
1,2,3-triselena[3]ferrocenophane
Cluster
Metal chalcogenide
Manganese carbonyl
Osmium carbonyl
Molecular structure
 
Description Reactions of 1,2,3-triselena[3]ferrocenophane with [Mn2(CO)(10)], [Fe(CO)(5)] and [Os-3(CO)(12)] have been investigated under photolytic or thermolytic conditions. Clusters with contrasting structures have been isolated from these reactions: [{Fe(eta-C5H4Se)(2)Mn(CO)(3)}(2)] (1), [Fe(eta-C5H4Se)(2)Fe-2(CO)(6)] (2), 1Fe(eta-C5H4Se)(2)OS3(CO)(10)] (3), [Fe(eta-C5H4Se)(2)(mu(2)-Se)Os-2(CO)(6)] (4) and [Fe(eta-C5H4Se)(2)(mu(3)-Se)Os-4(CO)(11)] (5). Formally, these new clusters are formed by substitution of the central selenium of 1,2,3-triselena[3] ferrocenophane by metal carbonyl units, as in 1-3 or insertion of two Os(CO)(3) groups or an Os-4(CO)(11) unit into the Se Se bond as in 4 and 5, respectively. (C) 2015 Elsevier B.V. All rights reserved.
 
Publisher ELSEVIER SCIENCE SA
 
Date 2016-01-15T04:21:56Z
2016-01-15T04:21:56Z
2015
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 794,266-273
0022-328X
1872-8561
http://dx.doi.org/10.1016/j.jorganchem.2015.07.005
http://dspace.library.iitb.ac.in/jspui/handle/100/17745
 
Language en