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An enantioselective total synthesis of Sch-725674

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Title An enantioselective total synthesis of Sch-725674
 
Creator RAMAKRISHNA, K
KALIAPPAN, KP
 
Subject PIPERIDINE
STRATEGIES
SCH725674
CORE
 
Description An enantioselective total synthesis of Sch-725674, a unique 14-membered macrolactone, has been accomplished in 13 steps. The step-wise dithiane alkylation served as a strategic step to assemble the upper and lower fragments of the molecule, whereas cross metathesis reaction, Yamaguchi macrolactonization and a substrate controlled stereoselective reduction are used as key steps to complete the total synthesis.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2016-01-15T06:55:09Z
2016-01-15T06:55:09Z
2015
 
Type Article
 
Identifier ORGANIC & BIOMOLECULAR CHEMISTRY, 13(1)234-240
1477-0520
1477-0539
http://dx.doi.org/10.1039/c4ob02136c
http://dspace.library.iitb.ac.in/jspui/handle/100/17985
 
Language en