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A stereoselective synthesis of the reported structure of polyporolide

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Field Value
 
Title A stereoselective synthesis of the reported structure of polyporolide
 
Creator PATIL, PH
FERNANDES, RA
 
Subject RING-CLOSING METATHESIS
HAGENS GLAND LACTONES
ASYMMETRIC EPOXIDATION
ALLYLIC ALCOHOLS
EPOXY ALCOHOLS
LIGAND CLASS
DIHYDROXYLATION
ACID
CATALYSTS
ANALOGS
 
Description Polyporolide, isolated from a basidiomycete, was assigned a 4-hydroxy-5-(1-hydroxyhexyl)-dihydrofuran-2- one structure with anti-placement of the three contiguous stereocenters. A stereoselective total synthesis of the reported structure of the natural product involving two different routes is presented. A comparison of the spectral data of the synthesized molecule indicates the need for structure revision of natural polyporolide.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2016-01-15T07:22:41Z
2016-01-15T07:22:41Z
2015
 
Type Article
 
Identifier RSC ADVANCES, 5(61)49189-49194
2046-2069
http://dx.doi.org/10.1039/c5ra07930f
http://dspace.library.iitb.ac.in/jspui/handle/100/18039
 
Language en