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One-pot regioselective synthesis of functionalized and fused furans from Morita-Baylis-Hillman and Rauhut-Currier adducts of nitroalkenes

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Title One-pot regioselective synthesis of functionalized and fused furans from Morita-Baylis-Hillman and Rauhut-Currier adducts of nitroalkenes
 
Creator MANE, V
KUMAR, T
PRADHAN, S
KATIYAR, S
NAMBOOTHIRI, INN
 
Subject MBH-TYPE REACTION
INTRAMOLECULAR MICHAEL ADDITION
THIOUREA-TERTIARY AMINE
PAAL-KNORR REACTION
CONJUGATED NITROALKENES
NITROALLYLIC ACETATES
CASCADE REACTIONS
DIASTEREOSELECTIVE SYNTHESIS
POLYSUBSTITUTED FURANS
ANTIMICROBIAL ACTIVITY
 
Description Highly functionalized and fused furans have been synthesized via cascade reactions of Morita-Baylis-Hillman and Rauhut-Currier adducts of nitroalkenes with active methylene compounds. The reactions involving S(N)2'-intramolecular Michael addition or Michael addition-intra-molecular nucleophilic substitution take place in a regioselective manner to afford synthetically and biologically useful furans in moderate to good yields.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2016-01-15T07:24:14Z
2016-01-15T07:24:14Z
2015
 
Type Article
 
Identifier RSC ADVANCES, 5(86)69990-69999
2046-2069
http://dx.doi.org/10.1039/c5ra11471c
http://dspace.library.iitb.ac.in/jspui/handle/100/18042
 
Language en