Thermoelectric transport and microstructure of optimized Mg2Si0.8Sn0.2
DSpace at IIT Bombay
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Title |
Thermoelectric transport and microstructure of optimized Mg2Si0.8Sn0.2
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Creator |
DE BOOR, J
GUPTA, S KOLB, H DASGUPT, T MULLER, E |
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Subject |
LATTICE VIBRATION FREQUENCIES
MAGNESIUM SILICIDE ELASTIC CONSTANTS MG2SI FABRICATION |
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Description |
Solid solutions of magnesium silicide and magnesium stannide exhibit excellent thermoelectric properties due to favorable electronic band structures and reduced thermal conductivity compared to the binary compounds. We have optimized the composition Mg2Si0.8Sn0.2 by Sb doping and obtained a thermoelectric figure of merit close to unity. The material comprises of several phases and exhibits intrinsic nanostructuring. Nevertheless, the main features of electronic transport can be understood within the framework of a single parabolic band model. Compared to Mg2Si we observe a comparable power factor, a drastically reduced thermal conductivity and an increased effective mass.
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Publisher |
ROYAL SOC CHEMISTRY
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Date |
2016-01-15T07:31:54Z
2016-01-15T07:31:54Z 2015 |
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Type |
Article
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Identifier |
JOURNAL OF MATERIALS CHEMISTRY C, 3(40)10467-10475
2050-7526 2050-7534 http://dx.doi.org/10.1039/c5tc01535a http://dspace.library.iitb.ac.in/jspui/handle/100/18057 |
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Language |
en
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