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Hybrid macrocycle formation and spiro annulation on cis-syn-cis-tricyclo[6.3.0.0(2,6)]undeca-3,11-dione and its congeners via ring-closing metathesis

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Title Hybrid macrocycle formation and spiro annulation on cis-syn-cis-tricyclo[6.3.0.0(2,6)]undeca-3,11-dione and its congeners via ring-closing metathesis
 
Creator KOTHA, S
CHINNAM, AK
ALI, R
 
Subject DIVERSITY-ORIENTED APPROACH
DIELS-ALDER REACTION
FISCHER INDOLE CYCLIZATION
HELICAL PRIMARY STRUCTURES
NATURAL-PRODUCT SYNTHESIS
LOW-MELTING MIXTURES
KEY STEPS
OLEFIN METATHESIS
ORGANIC-SYNTHESIS
CLAISEN REARRANGEMENT
aza-polyquiananes
Fischer indolization
macrocycles
ring-closing metathesis
spiropolyquinanes
 
Description We have developed a simple methodology to transform cis-syn-cis-triquinane derivative 2 into the diindole based macrocycle 6 involving Fischer indolization and ring-closing metathesis (RCM). Various spiro-polyquinane derivatives have been assembled via RCM as a key step.
 
Publisher BEILSTEIN-INSTITUT
 
Date 2016-01-15T10:36:47Z
2016-01-15T10:36:47Z
2015
 
Type Article
 
Identifier BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 11,1123-1128
1860-5397
http://dx.doi.org/10.3762/bjoc.11.126
http://dspace.library.iitb.ac.in/jspui/handle/100/18363
 
Language en