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Design and synthesis of fused polycycles via Diels-Alder reaction and ring-rearrangement metathesis as key steps

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Title Design and synthesis of fused polycycles via Diels-Alder reaction and ring-rearrangement metathesis as key steps
 
Creator KOTHA, S
RAVIKUMAR, O
 
Subject CLOSING METATHESIS
OLEFIN-METATHESIS
DERIVATIVES
RCM
HETEROCYCLES
SYSTEMS
SCOPE
ROM
Diels-Alder reaction
Grignard addition
ring-rearrangement metathesis
polycycles
 
Description Atom efficient processes such as the Diels-Alder reaction (DA) and the ring-rearrangement metathesis (RRM) have been used to design new polycycles. In this regard, ruthenium alkylidene catalysts are effective in realizing the RRM of bis-norbornene derivatives prepared by DA reaction and Grignard addition. Here, fused polycycles are assembled which are difficult to produce by conventional synthetic routes.
 
Publisher BEILSTEIN-INSTITUT
 
Date 2016-01-15T10:37:17Z
2016-01-15T10:37:17Z
2015
 
Type Article
 
Identifier BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 11,1259-1264
1860-5397
http://dx.doi.org/10.3762/bjoc.11.140
http://dspace.library.iitb.ac.in/jspui/handle/100/18364
 
Language en